Regioselective allene hydrosilylation catalyzed by N-heterocyclic carbene complexes of nickel and palladium.

نویسندگان

  • Zachary D Miller
  • Wei Li
  • Tomás R Belderrain
  • John Montgomery
چکیده

Regioselective methods for allene hydrosilylation have been developed, with regioselectivity being governed primarily by the choice of metal. Alkenylsilanes are produced via nickel catalysis with larger N-heterocyclic carbene (NHC) ligands, and allylsilanes are produced via palladium catalysis with smaller NHC ligands. These complementary methods allow either regioisomeric product to be obtained with exceptional regiocontrol.

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عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 135 41  شماره 

صفحات  -

تاریخ انتشار 2013